Browsing by Author "Eberlin, Marcos Nogueira"
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Intrinsic gas-phase electrophilic reactivity of Ccclic N-alkyl- and N-acyliminium ions
D'Oca, Marcelo Gonçalves Montes; Moraes, Luiz Alberto Beraldo; Pilli, Ronaldo Aloise; Eberlin, Marcos Nogueira (2001)he intrinsic gas-phase reactivity of cyclic N-alkyl- and N-acyliminium ions toward addition of allyltrimethylsilane (ATMS) has been compared using MS2 and MS3 pentaquadrupole mass spectrometric experiments. An order of ... -
Mannich-Type reactions in the Gas-Phase: the addition of Enol Silanes to cyclic N-Acyliminium Ions
Tomazela, Daniela Maria; Moraes, Luiz Alberto Beraldo; Pilli, Ronaldo Aloise; Eberlin, Marcos Nogueira (2002)The intrinsic gas-phase reactivity of cyclic N-acyliminium ions in Mannich-type reactions with the parent enol silane, vinyloxytrimethylsilane, has been investigated by double- and triple-stage pentaquadrupole mass ...