dc.contributor.author |
Fonseca, Alexandra de Souza |
|
dc.contributor.author |
Peres, Gisele Louro |
|
dc.contributor.author |
Storino, Tomás Garcia |
|
dc.contributor.author |
Bresolin, Leandro |
|
dc.contributor.author |
Gervini, Vanessa Carratu |
|
dc.date.accessioned |
2012-03-05T04:52:15Z |
|
dc.date.available |
2012-03-05T04:52:15Z |
|
dc.date.issued |
2010 |
|
dc.identifier.citation |
FONSECA, Alexandra de Souza et al. Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii). Química Nova, São Paulo, v. 33, n. 7, p.1453-1456, jun. 2010. Disponível em: <www.scielo.br/pdf/qn/v33n7/a06v33n7.pdf>. Acesso em: 30 dez. 2011. |
pt_BR |
dc.identifier.issn |
1453-1456 |
|
dc.identifier.uri |
http://repositorio.furg.br/handle/1/1825 |
|
dc.description.abstract |
The reaction of 4-(phenyl)thiosemicarbazide with isatin yielded a new ligand, isatin-3-(N4-
benzylthiosemicarbazone). Isatin-3-(N4-benzylthiosemicarbazone) deprotonated in ethanol/KOH reacts with an ethanolic solution
of Hg(NO3)2 to give a mercury complex. The compounds were characterized by IR and X-ray single crystal structure determination.
The X-ray studies revealed that the complex possesses a tetrahedral geometry with two deprotonated thiosemicarbazone ligands
coordenated. The ligand and its mercury complex crystallize in the monoclinic (P21/c) and triclinic (P-1) crystal system, respectively. |
pt_BR |
dc.language.iso |
por |
pt_BR |
dc.rights |
open access |
pt_BR |
dc.subject |
Mercury complex |
pt_BR |
dc.subject |
Thiosemicarbazone |
pt_BR |
dc.subject |
Hydrogen bonds |
pt_BR |
dc.title |
Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii) |
pt_BR |
dc.title.alternative |
Synthesis and structural characterization of the ligand Isatin-3-(n4-benzylthiosemicarbazone) and its Mercury(ii) complex. |
pt_BR |
dc.type |
article |
pt_BR |