Reações intramoleculares como modelos não miméticos de catálise enzimática

Gesser, José Carlos; Yunes, Santiago; Clementin, Rosilene Maria; Aguilera, Faruk Jose Nome


This review gives a critical idea on the importance of intramolecular reactions as models for enzymatic catalysis. Intramolecular lactonizations, ester and amide hydrolysis studies result in theories which try to explain the difference between intermolecular, intramolecular and enzyme reactions and rationalize the enhancement promoted by these biological catalyst.

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  • EQA - Artigos Publicados em Periódicos