Show simple item record Pederzolli, Fernanda Rosi Soares Bresolin, Leandro Beck, Johannes Daniels, Jorg Oliveira, Adriano Bof de 2014-09-23T23:30:37Z 2014-09-23T23:30:37Z 2012
dc.identifier.citation PEDERZOLLI, Fernanda Rosi Soares et al. [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II). Acta Crystallographica Section E, v. 68, n. 9, p. 1138-1138, 2012. Disponível em: <>. Acesso em: 23 set. 2014. pt_BR
dc.identifier.issn 1600-5368
dc.description.abstract The reaction of 5-bromosalicylaldehyde thiosemicarbazone with nickel acetate tetrahydrate and pyridine yielded the title compound, [Ni(C8H6BrN3OS)(C5H5N)]. The NiII atom is four-coordinated in a square-planar environment by one deprotonated dianionic thiosemicarbazone ligand, acting in a tridentate chelating mode through N, O and S atoms forming two metalla-rings, and by one pyridine molecule. The complex molecules are linked into dimers by pairs of centrosymmetrical N-H...N interactions. In addition, molecules are connected through intermolecular Br...Br interactions [3.545 (1) Å], forming chains along the b-axis direction. pt_BR
dc.language.iso eng pt_BR
dc.rights open access pt_BR
dc.subject Single-crystal X-ray study pt_BR
dc.subject T = 293 K pt_BR
dc.subject Mean (C–C) = 0.004 A˚ pt_BR
dc.subject R factor = 0.031 pt_BR
dc.subject wR factor = 0.083 pt_BR
dc.subject Data-to-parameter ratio = 17.0 pt_BR
dc.title [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II) pt_BR
dc.type article pt_BR
dc.identifier.doi 10.1107/S1600536812028917 pt_BR

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