dc.contributor.author |
Beck, Paulo Henrique |
|
dc.contributor.author |
Santos, Juliane Marques dos |
|
dc.contributor.author |
Kuhn, Bruna Luiza |
|
dc.contributor.author |
Moreira, Dayse das Neves |
|
dc.contributor.author |
Flores, Alex Fabiani Claro |
|
dc.contributor.author |
Martins, Marcos Antonio Pinto |
|
dc.contributor.author |
D'Oca, Marcelo Gonçalves Montes |
|
dc.contributor.author |
Piovesan, Luciana Almeida |
|
dc.date.accessioned |
2014-11-18T22:52:37Z |
|
dc.date.available |
2014-11-18T22:52:37Z |
|
dc.date.issued |
2012 |
|
dc.identifier.citation |
BECK, Paulo Henrique et al. Regiospecific synthesis of new fatty N-acyl trihalomethylated pyrazoline derivatives from fatty acid methyl esters (FAMEs). Journal of the Brazilian Chemical Society, v. 23, n. 11, p. 2122-2127, 2012. Disponível em: <http://www.scielo.br/pdf/jbchs/v23n11/aop096_12.pdf>. Acesso em: 10 jun. 2014 |
pt_BR |
dc.identifier.issn |
0103-5053 |
|
dc.identifier.uri |
http://repositorio.furg.br/handle/1/4671 |
|
dc.description.abstract |
Uma série de novas pirazolinas N-acil trialometiladas derivadas de ésteres metílicos de
ácidos graxos foi sintetizada por reação de ciclocondensação entre hidrazidas graxas e 4-alcóxi-1,1,1‑trialometil-3-alquen-2-onas. Ciclizações eficientes e regioespecíficas catalisadas por BF3·MeOH levaram aos produtos desejados em rendimentos de bons a excelentes e alto grau de pureza. |
pt_BR |
dc.description.abstract |
A series of new fatty N-acyl trihalomethylated pyrazoline derivatives from fatty acid methyl
esters was synthesized by the cyclocondensation of respective fatty hydrazides with 4-alkoxy-1,1,1‑trialomethyl-3-alquen-2-ones. Efficient and regiospecific cyclizations catalyzed by BF3·MeOH gave the desired products in good to excellent yields and at high purity. |
pt_BR |
dc.language.iso |
eng |
pt_BR |
dc.publisher |
Journal of the Brazilian Chemical Society |
pt_BR |
dc.rights |
open access |
pt_BR |
dc.subject |
N-acyl hydrazine |
pt_BR |
dc.subject |
FAMEs |
pt_BR |
dc.subject |
4-alkoxy-1,1 |
pt_BR |
dc.subject |
1-trialomethyl-3-alquen-2-ones |
pt_BR |
dc.subject |
N-acyl trialomethylated pyrazoline |
pt_BR |
dc.title |
Regiospecific synthesis of new fatty N-acyl trihalomethylated pyrazoline derivatives from fatty acid methyl esters (FAMEs) |
pt_BR |
dc.type |
article |
pt_BR |