Electrochemical Oxidation of N - p -Toluenesulfinamides

D'Oca, Marcelo Gonçalves Montes; Russowsky, Dennis; Canto, Karen Fabiano Santos do; Gressler, Tanara; Gonçalves, Reinaldo Simões


Contrasting and interesting electrochemical behavior is observed in anodic oxidation of N-substituted p-toluenesulfinamides under controlled current conditions. For sulfinamides derived from secondary alkylamines and primary arylamines, the N-sulfinyl group is removed and the corresponding amines are formed; for sulfinamides derived from primary alkylamines, sulfur oxidation yields the corresponding sulfonamides in good yields.

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