Fonseca, Alexandra de Souza; Gervini, Vanessa Carratu; Bresolin, Leandro; Locatelli, Aline; Oliveira, Adriano Bof de


The reaction of cadmium acetate dihydrate with 2-acetylpyridine (4-phenylthiosemicarbazone) yielded the title compound, [Cd(C14H13N4S)2]. The CdII atom is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, molecules are connected through inversion centers via pairs of N-H...S interactions, building a one-dimensional hydrogen-bonded polymer along [0-1-1].

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