Show simple item record Fonseca, Alexandra de Souza Gervini, Vanessa Carratu Bresolin, Leandro Locatelli, Aline Oliveira, Adriano Bof de 2014-09-23T23:03:35Z 2014-09-23T23:03:35Z 2012
dc.identifier.citation FONSECA, Alexandra de Souza et al. Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium. Acta Crystallographica Section E, v. 68, n. 5, p. 635-636, 2012. Disponível em:<>. Acesso em: 23 set. 2014. pt_BR
dc.identifier.issn 1600-5368
dc.description.abstract The reaction of cadmium acetate dihydrate with 2-acetylpyridine (4-phenylthiosemicarbazone) yielded the title compound, [Cd(C14H13N4S)2]. The CdII atom is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, molecules are connected through inversion centers via pairs of N-H...S interactions, building a one-dimensional hydrogen-bonded polymer along [0-1-1]. pt_BR
dc.language.iso eng pt_BR
dc.rights open access pt_BR
dc.subject Single-crystal X-ray study pt_BR
dc.subject T = 296 K pt_BR
dc.subject Mean (C–C) = 0.005 A˚ pt_BR
dc.subject R factor = 0.038 pt_BR
dc.subject wR factor = 0.080 pt_BR
dc.subject Data-to-parameter ratio = 22.6 pt_BR
dc.title Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium pt_BR
dc.type article pt_BR
dc.identifier.doi 10.1107/S1600536812016558 pt_BR

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